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91.
Nonlinear coupling between Langmuir waves with finite amplitude dispersive dust acoustic perturbations is considered. It is shown that the interaction is governed by a pair of coupled nonlinear differential equations. Numerical results reveal the formation of Langmuir envelope solitons composed of the dust density depression created by the ponderomotive force of bell-shaped Langmuir wave envelops. The associated ambipolar potential is positive. The present nonlinear theory should be able to account for the trapping of large amplitude Langmuir waves in finite amplitude dust density holes. This scenario may appear in Saturn's dense rings, and the Cassini spacecraft should be able to observe fully nonlinear cavitons, as presented herein. Furthermore, we propose that new electron-beam plasma experiments should be conducted to verify our theoretical prediction. 相似文献
92.
An analytic theory for the Knudsen self-diffusivity D(s) of hard spheres in an atomically rough slit-shaped pore is presented which quantitatively matches simulation results. The theory assumes that, due to chaotic molecular trajectories caused by surface morphology, collisions of gas molecules with the wall are partly diffuse and partly specular, the relative magnitude of each depending upon the magnitude of the tangential momentum accommodation coefficient f. The theory thus represents a universal Knudsen fluctuation-dissipation correlation between longitudinal momentum loss and diffusivity that can simplify efforts to estimate D(s). It is also found that D(s) computed using Maxwell's theory of slip, in which collisions with the walls are assumed to be purely diffuse or specular, overpredicts the simulated D(s) by a large margin. 相似文献
93.
Stigmasterol, a plant product, has been used as a surfactant to generate liquid membranes supported on a cellulose acetate matrix. Electrochemical characterization of the membrane has been attempted with a view to simulating its behavior with natural membranes by measuring membrane potentials and membrane conductance. The selectivity of cellulose acetate membrane kept in contact with magnesium chloride solutions of different mean concentrations has been found to change from anion to cation. Transport numbers have been estimated from membrane potential data. Permselectivity and fixed charge density values for the cellulose acetate membrane with and without stigmasterol have been determined from transport numbers. The variation of these parameters with concentration and pH has also been examined. 相似文献
94.
N.L. Tsintsadze P.K. Shukla L. Stenflo 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,23(1):109-115
The electroweak coupling between intense neutrino beams and strongly degenerate relativistic dense electron-positron magnetoplasmas
is considered. The intense neutrino bursts interact with the plasma due to the weak Fermi interaction force, and their dynamics
is governed by a kinetic equation. Our objective here is to develop a kinetic equation for a degenerate neutrino gas and to
use that equation to derive relativistic magnetohydrodynamic equations. The latter are useful for studying numerous collective
processes when intense neutrino beams nonlinearly interact with degenerate, relativistic, dense electron-positron plasmas
in strong magnetic fields. If the number densities of the plasma particles are of the order of 1033 cm-3, the pair plasma becomes ultra-relativistic, which strongly affects the potential energy of the weak Fermi interaction. The
new system of equations allows several neutrino-driven streaming instabilities involving new types of relativistic Alfvén-like
waves. The relevance of our investigation to the early universe and supernova explosions is discussed.
Received 11 September 2002 Published online 4 February 2003
RID="a"
ID="a"Permanent address: Department of Physics, Tbilisi State University, Chavchavadze 3, Tbilisi 38028, Georgia.
RID="b"
ID="b"Also at the Department of Plasma Physics, Ume? University, 90187 Ume?, Sweden; and the Center for Interdisciplinary Plasma Science,
Max-Planck Institut für Plasmaphysik und extraterrestrische Physik, Postfach 1312, 85741 Garching, Germany. e-mail: ps@tp4.ruhr-uni-bochum.de
RID="c"
ID="c"Permanent address: Department of Plasma Physics, Ume?University, 90187 Ume?, Sweden. 相似文献
95.
96.
Shukla PK 《Physical review letters》2000,84(23):5328-5330
It is shown that dust lattice waves (DLWs) become parametrically unstable in a turbulent dusty plasma sheath that contains random-phase ion plasma waves. Physically, the parametric instability arises because of the nonlinear coupling between ion plasma waves and DLWs. The parametric instability is identified as the possible reason for the observed "sublimation" transition of the plasma crystal from a solid to a gaslike state. 相似文献
97.
We consider reflection of electromagnetic waves from layered structures with various dielectric and magnetic properties, including metamaterials. Assuming periodic variations in the permittivity, we find that the reflection is in general anomalous. In particular, we note that the specular reflection vanishes and that the incident energy is totally reflected in the backward direction, when the conditions for resonant excitation of leaking surface waves are fulfilled. 相似文献
98.
Chetan R. Singh Gaurav Gupta Ruth Lohwasser Sebastian Engmann Jens Balko Mukundan Thelakkat Thomas Thurn‐Albrecht Harald Hoppe 《Journal of Polymer Science.Polymer Physics》2013,51(12):943-951
A series of well‐defined poly(3‐hexylthiophene)s (P3HT) of different molecular weight (MW) and high regioregularity was investigated for charge transport properties in as‐cast and melt‐crystallized films. The semicrystalline structure of the P3HT was characterized by X‐ray scattering and Atomic force microscopy. Crystallization by cooling from the melt led to a substantial increase in crystallinity and a stronger alignment of the crystals in comparison to as‐cast films. The increase in crystallinity went along with an increase in hole mobility of up to an order of magnitude as measured by the space charge limited current method. Additionally, the hole mobility depended on the long period of P3HT lamellae and consequently on the MW. In compliance with the long period, the charge carrier mobility first increased with the MW before decreasing again at the onset of chain folding. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2013 , 51, 943–951 相似文献
99.
R.K. Shukla Atul Kumar Alok Shukla Kirti Srivastava 《Journal of Molecular Liquids》2008,140(1-3):117-122
Density, ultrasonic velocity, surface tension, excess volume and viscosity of quaternary non-electrolyte solution n-pentane+tolune+n-heptane+cyclohexane has been experimentally determined at 25 °C over a wide range of composition. Assuming a quaternary fluid solution to be made of six binaries, a statistical approach of Prigogine–Flory–Patterson (PFP) theory has been extended to develop the expressions for dynamic viscosity, surface tension excess volume and ultrasonic velocity of quaternary fluid system. A reasonable agreement has been achieved between theory and experiment. An attempt has also bee made to explain the nature of molecular interactions involved in the light of excess thermodynamic functions whose sign and magnitude depend upon the chain length and size of the component fluids and also studied the role of order breakers (toluene and cyclohexane) on these properties. 相似文献
100.
Kinetic and thermodynamic investigations were performed for a mixed aqueous-organic, 1:1 (v/v) water–1,4-dioxane medium, which was found to be an efficient solvent for the interaction of a neutral dichlorotris(triphenylphosphine) ruthenium(II), RuCl2(PPh3)3 complex with carbon monoxide at atmospheric pressure. During the interaction, RuCl2(PPh3)3 dissociates to a neutral complex dichlorobis(triphenylphosphine) ruthenium(II), RuCl2(PPh3)2, by losing a coordinated PPh3 ligand and RuCl2(PPh3)2 coordinates with CO to form an in situ carbonyl complex RuCl2(CO)(PPh3)2. The in situ formed carbonyl complex RuCl2(CO)(PPh3)2 was thoroughly characterized by equilibrium, spectrophotometric, IR, and electrochemical techniques. Under equilibrium conditions, the rate and dissociation constants for the dissociation of PPh3 from RuCl2(PPh3)3 were found to be favorable for the formation of the carbonyl complex RuCl2(CO)(PPh3)2. The rates of complexation for the formation of RuCl2(CO)(PPh3)2 were found to follow an overall second-order kinetics being first order in terms of the concentrations of both carbon monoxide and RuCl2(PPh3)2. The determined activation parameters corresponding to the rate constant (ΔH# = 35.9 ± 2.5 kJ mol−1 and ΔS# = −122 ± 6 J K−1 mol−1) and thermodynamic parameters corresponding to the formation constant (ΔH° = −33.5 ± 4.5 kJ mol−1, ΔS° = −25 ± 8 J K−1 mol−1, and ΔG° = −25.7 ± 2.0 kJ mol−1) were found to be highly favorable for the formation of the complex RuCl2(CO)(PPh3)2. © 2008 Wiley Periodicals, Inc. Int J Chem Kinet 40: 359–369, 2008 相似文献